The Reverend who officiated Angelina Jolie and Billy Bob Thornton's May 2000 wedding is sharing new details of the A-list couple's Las Vegas nuptials — including the pair's ultra dressed-down "I Do" attire!

In a newly released wedding photo, Angelina, 39, is seen standing next to Billy Bob, 59, and Reverend Jim Hamilton wearing a casual pair of light-wash jeans, a gray sleeveless T-shirt and brown boots. For the occasion, the bride donned light makeup and had her hair pulled back in a ponytail.

angelina jolie and billy bob thornton

Angelina and Billy Bob in January 2002.

The photo, obtained by the 'Daily Mail,' additionally shows the groom's similarly simplistic outfit including a hat, patterned shirt, black slacks and a pair of matching black boots.

The eccentric pair first met while filming the 1999 comedy 'Pushing Tin' and eloped in Sin City after dating for only two months. They later divorced in May 2003.

Related Story: Angelina Jolie Says She Finally Found a "Real Man" in Husband Brad Pitt

Since then, the actress has tied the knot with Brad Pitt, 51, with whom she has six children; Maddox, 13, Pax, 11, Zahara, 10, Shiloh, 8, and twins Knox and Vivienne, 6. After splitting with Angelina — who was his fifth wife — Billy Bob married his long-time love Connie Angland in October 2014.

angelina jolie and billy bob thornton spouses

Angelina with Brad (left) and Billy Bob and Connie (right). (Photo Credits: Getty Images)

"I'm very happy for them that they've both happily married again. I am glad to hear Billy Bob has married again, of course everybody knew about Angelina and Brad. I was glad Angelina married Brad, I like Brad Pitt, his movies and he's a real decent human being and she is too," Reverend Hamilton said of the former couple in a new interview.

"I hope they both have very long and happy marriages and congratulate them both. I hope this is the last one for both of them and they have found their true soulmates this time," he told the 'Daily Mail.'