In the summer of 2004, the pair met on the set of Mr. & Mrs. Smith. The following March, Brad's wife at the time, Jennifer Aniston, filed for divorce. Though the actor has denied having an on-set romance with Angelina, many speculate they got up close and personal before his separation from Jen.
In April 2005, paparazzi photos captured Brad, Angelina and her adopted son Maddox on a beach in Kenya, fueling rumors of a relationship between the two. That July, the actress adopted her second child Zahara from Ethiopia, and just four short months later, Brad was photographed carrying the little girl as he and Angie arrived in Japan.
After adopting son Pax from Vietnam in March 2007, Angelina confirmed in May 2008 that she was expecting twins with Brad (her bump had already been showing for quite some time). The brunette beauty gave birth to son Knox and daughter Vivienne on July 12, 2008, in Nice, France.
The big, happy family (apart from youngest daughter Vivienne) attended the LA premiere of Maleficent on May 28, 2014 to support matriarch Angelina. From left: Pax, Brad, Angie, Zahara, Knox, Shiloh and Maddox.